Transfer hydrogenation with a ferrocene diamide ruthenium complex |
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| Authors: | Elliott Andrew G Green Aaron G Diaconescu Paula L |
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| Affiliation: | Department of Chemistry & Biochemistry, University of California, Los Angeles, 607 Charles E. Young Dr. E., Los Angeles, CA 90095, USA. |
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| Abstract: | The use of a 1,1'-ferrocenediamide ruthenium complex as a mediator for base-free transfer hydrogenation is reported. Ketones were transformed to their respective alcohols at room temperature in 36-99% conversions with turnover frequencies up to 339 h(-1). |
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