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Investigation of the crystallization kinetics of cyclotetramethylenetetranitramine from nitric acid by microcalorimetry
Authors:Xijun Chen   Zhibin Li  Rongzu Hu
Affiliation:

a Xian Modern Chemistry Research Institute Xian 710061, Shaanxi People's Republic of China

Abstract:The total heat produced and the rate of heat production during the crystallization of cyclotetramethylenetetranitramine (HMX) from nitric acid are measured using a conduction calorimeter. The data of thermograms of HMX are treated based on the dislocation theory model. The results show that the crystal growth process of HMX accords with the dislocation theory.
Keywords:Crystallization kinetics   Dislocation theory   HMX   Microcalorimetry
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