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In-Situ Investigation of Discolouration Processes Between Historic Oil Paint Pigments
Authors:Rachel White  Matthew R Phillips  Paul Thomas  Richard Wuhrer
Institution:(1) Microstructural Analysis Unit, University of Technology Sydney, PO Box 123, 2007 Broadway, New South Wales, Australia;(2) Department of Chemistry, Materials and Forensic Science, University of Technology Sydney, 2007 Broadway, New South Wales, Australia
Abstract:Discolouring interactions between paint pigments have been observed since the mid 19th century. The source of some of these discolourations is the production of copper sulfides from an interaction between cadmium sulfide pigments and copper containing pigments. In this work, the discolouring interaction between cadmium yellow and malachite pigments was observed dynamically using the environmental scanning electron microscope (ESEM).
Keywords:: Pigment interaction  oil paintings  ESEM  in-situ hydration  cadmium yellow  
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