Bridging the gap between solution and solid state studies in polyoxometalate chemistry: discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties |
| |
| Authors: | Miras Haralampos N Long De-Liang Kögerler Paul Cronin Leroy |
| |
| Affiliation: | Department of Chemistry, University of Glasgow, University Avenue, UKG12 8QQ. |
| |
| Abstract: | A family of polyoxometalates with the composition [H2V3M17O62](6-) features a Dawson-like architecture containing two tetrahedral {VVO4} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {MVI17VIVO54} cage and these clusters were first discovered using mass spectrometry. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
