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An ionic liquid-coordinated palladium complex: a highly efficient and recyclable catalyst for the Heck reaction
Authors:Xiao Ji-Chang  Twamley Brendan  Shreeve Jean'ne M
Institution:Department of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, USA.
Abstract:structure: see text] The monoquaternary product of 2,2'-biimidazole with iodobutane is an ionic liquid that acts as both the solvent and ligand for catalytic reactions. A new palladium complex was prepared by adding PdCl(2) to this ionic liquid to form a catalytic solution that is effective for Heck reactions with good recyclability.
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