Thermochemical parameters of adducts of cadmium(II) halides with bidentate N- and O-ligands |
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Authors: | P O Dunstan |
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Institution: | 1.Instituto de Química,Universidade Estadual de Campinas,Campinas,Brazil |
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Abstract: | The adducts CdX2(L-L)], where X = Cl, Br, I; L-L = 2,2’-bipyridine (bipy) or 2,2′-bipyridine N,N′-dioxide (bipyNO) have been synthesized and characterized by melting points, elemental analysis, thermal analysis, and IR
spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermochemical
parameters were determined. The mean standard enthalpies of the cadmium-nitrogen and cadmium-oxygen bonds have been estimated. |
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Keywords: | |
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