Near-infrared quantum cutting in transparent nanostructured glass ceramics |
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| Authors: | Chen Daqin Wang Yuansheng Yu Yunlong Huang Ping Weng Fangyi |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China. |
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| Abstract: | Quantum cutting downconversion involving the emission of two near-infrared photons for each blue photon absorbed is realized in transparent glass ceramics with embedded Pr3+/Yb3+: beta-YF3 nanocrystals. On excitation of Pr3+ ions with a visible photon at 482 nm, Yb3+ ions emit two near-infrared photons at 976 nm through an efficient cooperative energy transfer from Pr3+ to Yb3+, with optimal quantum efficiency close to 200%. The development of the near-infrared quantum cutting transparent glass ceramic could open a route to enhance the energy efficiency of the silicon solar cell by converting one blue solar photon to two near-infrared ones. |
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