Sur l'acylation des méthylfluorènes IV. [1] Benzoylation du méthyl-4-fluorène |
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Authors: | Louis Chardonnens,Roland Dousse,Ern Horwath |
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Affiliation: | Louis Chardonnens,Roland Dousse,Ernö Horwath |
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Abstract: | Benzoylation of 4-methylfluorene according to Friedel-Crafts in carbon disulfide with aluminium chloride yielded two benzoyl derivatives: 5-methyl-2-benzoyl-fluorene (II) (major product), and 4-methyl-2-benzoyl-fluorene (III). By oxidation II and III gave the corresponding 9-oxo-derivatives, the structure of the last compounds being proved by an independent way. |
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