Many-body interactions between particles in a polydisperse polymer fluid |
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Authors: | Woodward Clifford E Forsman Jan |
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Affiliation: | School of Physical, Environmental and Mathematical Sciences, University College, University of New South Wales, ADFA, Canberra, Australian Capital Territory 2600, Australia. c.woodward@adfa.edu.au |
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Abstract: | We use a continuum chain model and develop an analytical theory for the interaction between many spheres immersed in a fluid of ideal polydisperse polymers. Assuming local spherical symmetry of the polymer field about each particle, combined with a local approximation, compact expressions are derived for the many-body interaction between the spheres. We use a mean-field approximation to investigate the fluid-fluid phase diagram for the mixture. |
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