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Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution: a sharp phase transition at the lower critical solution temperature
Authors:Ono Yousuke  Shikata Toshiyuki
Affiliation:Department of Macromolecular Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Abstract:The number of hydrated water molecules per poly(N-isopropylacrylamide) monomer unit in homogeneous aqueous solution was determined to be 11 exactly and anew below the lower critical solution temperature of 32 degrees C employing high-frequency dielectric relaxation techniques.
Keywords:
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