The Er and Yb Complexes with Silicon-Containing Phosphates and Fluorine-Containing Phosphine Oxide: Synthesis,Spectra, and Films |
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| Authors: | Semenov V V Cherepennikova N F Klapshina L G Lopatin M A Mushtina T G Makarenko N P Khorshev S Ya Domrachev G A Douglas W E Bushuk B A |
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| Institution: | (1) Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603600, Russia;(2) Université Montpellier II, 34095 Montpellier cedex 5, France;(3) Stepanov Institute of Physics, Belarussian Academy of Sciences, Minsk, Belarus |
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| Abstract: | Three new silicon- and fluorine-containing ligands, namely bis(dimethylamido)(3-triethoxysilylpropylamido)phosphate O=P(NMe2)2NHCH2CH2CH2Si(OEt)3, diphenyl(3-triethoxysilylpropylamido)phosphate O=P(OPh)2NHCH2CH2CH2Si(OEt)3, and tris(3,3,3-trifluoropropyl)phosphine oxide O=P(CH2CH2CF3)3 are synthesized. The erbium and ytterbium complexes with amine, phosphate, and phosphine oxide ligands Ln(NH2R)3Cl3, LnO=P(NMe2)2NHR]3Cl3, LnO=P(OPh)2NHR]3Cl3 (R=CH2CH2CH2Si(OEt)3), LnO=P(OPh)3]3Cl3, LnO=P(CH2CH2CF3)3]3Cl3 are produced and their electronic absorption spectra and photoluminescence spectra are studied. The silicon-containing compounds form transparent thermostable films on silicate glass or quartz surface. |
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