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Substituted dipyridylpyridazine rhodium(III) complexes
Authors:Zaghal  Mukarram H.  Abu-Obeid  Mona A.  Atfah  Mohammad A.  El-Qisairi  Arab K.  Qaseer  Hanan A.  Ali  Basem F.
Affiliation:(1) Department of Chemistry, Yarmouk University, Irbid, Jordan;(2) Department of Chemistry, Mu'tah University, Mu'tah, Jordan;(3) Department of Chemistry, Al-al Bayt University, Mafraq, Jordan
Abstract:3,6-Bis(2prime-pyridyl)pyridazine derivatives (n-dppn) react with hydrated rhodium(III) chloride and bromide (prepared in situ) to give cis-[Rh(n-dppn)2Cl2]PF6·xH2O (n = 5, 6, 7, 8) and cis-[Rh(n-dppn)2Br2]Br·xH2O (n = 5, 7) complexes, which have been characterized by elemental analyses, conductivity measurements, i.r., electronic and 1H- and 13C-n.m.r. spectra.
Keywords:
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