| [Mn(H2O)4(NCS)2](18-冠-6)的分子和晶体结构 |
| |
| 引用本文： | 张文兴,樊悦朋,杜高英. [Mn(H2O)4(NCS)2](18-冠-6)的分子和晶体结构[J]. 化学学报, 1987, 45(12): 1143-1146 |
| |
| 作者姓名： | 张文兴 樊悦朋 杜高英 |
| |
| 作者单位： | 山东大学化学系 |
| |
| 摘 要： | 报导了[Mn(H2O)4(NCS)2](18-冠-6)单晶的X射线结构分析.它的晶体正交晶系.锰(II)与两个硫氰酸根,四个水分子配合形成顺式八面体的配位分子,并通过其中的水分子与18-冠-6以氢键结合.
|
| 关 键 词： | 晶体结构测定 Ｘ射线衍射分析 冠式化合物 水络合物 过渡金属络合物 锰络合物 硫氰酸根络合物 |
The molecular and crystal structure of [Mn(H2O)4(NCS)2] |
| |
| ZHANG WENXING,FAN YUEPENG,DU GAOYING. The molecular and crystal structure of [Mn(H2O)4(NCS)2][J]. Acta Chimica Sinica, 1987, 45(12): 1143-1146 |
| |
| Authors: | ZHANG WENXING FAN YUEPENG DU GAOYING |
| |
| Abstract: | The title compound is orthorhombic with space group Pnma and a 9.172(1), b 13.457(3), c 19.303(4) ? with d. (calcd.) = 1.42 for Z = 4. The structure was solved by heavy atom method and solved by least squares to R = 0.031. The crown ether does not coordinate directly with the Mn atom. The 4 water mols. and two thiocyanates from a cis distorted octahedral with Mn(II), and coordinate with 18-crown-6 through H-bonds. |
| |
| Keywords: | CRYSTAL STRUCTURE DETERMINATION X-RAY DIFFRACTION ANALYSIS CROWN ETHER COMPOUNDS AQUO COMPLEX TRANSITION METAL COMPLEX MANGANESE COMPLEX THIOCYANATO COMPLEX |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
|
点击此处可从《化学学报》下载全文 |
