Macrocycle formation by proton-template-induced dimerization of complexes with (alkoxoimino)pyridine |
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| Authors: | Álvarez Celedonio M García-Rodríguez Raúl Martín-Alvarez Jose M Miguel Daniel Turiel José A |
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| Institution: | IU CINQUIMA, Química Inorgánica, Universidad de Valladolid, E-47005 Valladolid, Spain. |
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| Abstract: | The existence of a strong hydrogen bond between two molecules of an (alkoxoimino)pyridinemanganese(I) complex induces their dimerization and the formation of a metallamacrocycle. The expected intramolecular attack of the alkoxo moiety is disfavored. |
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