Phenacenes from Diels-Alder trapping of photogenerated o-xylylenols: phenanthrenes and benzo[e]pyrene bisimide |
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Authors: | Ilhan Faysal Tyson Daniel S Meador Michael A |
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Institution: | Ohio Aerospace Institute, Cedar Point Road, Cleveland, Ohio 44135, USA. |
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Abstract: | structure: see text] The synthesis of phenanthrene and benzoe]pyrene bisimides, 1 and 2, was accomplished via the Diels-Alder trapping of sterically congested o-xylylenols photochemically generated from 3,6-dibenzoyl-o-xylene and 1,4-dibenzoyl-9,10-dihydroanthracene, respectively. Absorption and emission from 2 are red-shifted from 1 and unsubstituted benzoe]pyrene. The fluorescence quantum yield for 2 is an order of magnitude lower than that of 1 and comparable to that of the parent benzoe]pyrene. |
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