SERS Investigation on the Polymerization of Carbazolyl-diacetylene Monolayers on Gold Surfaces |
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| Authors: | Maurizio Muniz-Miranda Emilia Giorgetti Giancarlo Margheri Tommaso Del Rosso Stefano Sottini Anna Giusti Marina Alloisio |
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| Affiliation: | 1. Dipartimento di Chimica, Università di Firenze, Via della Lastruccia 3, 50019, Sesto Fiorentino, Italy;2. Istituto dei Sistemi Complessi, CNR, Via Panciatichi 64, 50127 Firenze, Italy;3. Dipartimento di Chimica e Chimica Industriale, Università di Genova, Via Dodecaneso 31, 16146 Genova, Italy |
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| Abstract: | Surface Enhanced Raman Scattering experiments were performed on self-assembled carbazolyl-diacetylene monolayers chemisorbed on smooth gold substrates and UV irradiated. The Raman enhancement was ensured by depositing silver colloidal nanoparticles, which strongly increase the surface roughness. The co-existence of two polymer phases, characterized by different degree of order in the polymeric backbone, was detected by SERS results, which suggest a polymerization scheme with conjugated triple bonds nearly parallel to the plane of the metal surface. |
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| Keywords: | AFM gold nanoparticles polymerization SERS |
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