Isolation and Identification of Residual Chromophores in Cellulosic Materials |
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Authors: | Thomas Rosenau Antje Potthast Andreas Hofinger Paul Kosma |
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Affiliation: | Department of Chemistry and Christian-Doppler-Laboratory, University of Natural Resources and Applied Life Sciences Vienna (BOKU), Muthgasse 18, 1190 Vienna, Austria, Fax: +43-1-36006 6059 |
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Abstract: | A general procedure was developed for the isolation of residual chromophores in or on cellulosic material, which were hitherto inaccessible to structure elucidation due to their extremely low content in the ppb concentration scale. It is applicable to cellulosic pulp, cellulosic fibers (viscose, Lyocell) and cellulose derivatives (acetate, carbonyl-labeled cellulose) as well. The chromophore identification comprises treatment of the cellulosic material with boron trifluoride – acetic acid complex (BF3*2HOAc) containing sulfite, chromatographic separation of the resulting chromophore-containing mixture, and structure determination of the main constituents by NMR / MS and comparison to authentic samples. Both adsorbed and covalently bound aromatic and quinoid compounds are selectively released by the treatment. Covalent ester, ether and secondary alkyl links between chromophore and cellulose are broken. Two cellulosic example substrates have been analyzed for their chromophore content: Lyocell fibers and non-bleached viscose fibers, and up to eleven chromophores per sample have been identified. |
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Keywords: | cellulose chromophores fibers pulp quinines trace analysis |
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