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| 亚酞菁铜的合成与表征 | |
| 引用本文： | 夏道成,姚纪欢,白青龙,程传辉,夏到鹏,刘立峰,范昭奇,杜国同. 亚酞菁铜的合成与表征[J]. 山西大学学报(自然科学版), 2009, 32(3) |
| 作者姓名： | 夏道成 姚纪欢 白青龙 程传辉 夏到鹏 刘立峰 范昭奇 杜国同 |
| 作者单位： | 1. 运城学院化学系,山西,运城,044000;大连理工大学物理与光电工程学院,辽宁,大连,116023 2. 运城学院化学系,山西,运城,044000 3. 大连理工大学物理与光电工程学院,辽宁,大连,116023 4. 吉林永吉四中,吉林,永吉,132200 5. 吉林永吉实验高中,吉林,永吉,132200 6. 大连理工大学物理与光电工程学院,辽宁,大连,116023;吉林大学集成光电子国家重点实验室物理学院,吉林,长春,130012 |
| 摘 要： | 新合成了亚酞菁铜.把1,3-二亚胺基异吲哚啉、钼酸铵和二水乙酸合铜在喹啉里加热,加入催化剂量的1,8-二氮杂-双环(5,4,O)十一碳烯-7(DBU)进行反应.反应完毕后,通过索氏提取,然后用柱色层分离,得到灰褐色产物.通过质谱分析和元素分析数据证实,灰褐色产物就是目标化合物亚酞菁铜.根据亚酞菁铜分子裂解质谱图,还初步分析了亚酞菁铜分子的裂解过程,首次给出亚酞菁铜合成的反应机理. |
| 关 键 词： | 酞菁 亚酞菁铜 反应机理 |
Synthesis and Characterizations of Sub-Phthalocyanine Copper |
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| XIA Dao-cheng,YAO Ji-huan,BAI Qing-long,CHENG Chuan-hui,XIA Dao-peng,LIU Li-feng,FAN Zhao-qi,DU Guo-tong. Synthesis and Characterizations of Sub-Phthalocyanine Copper[J]. Journal of Shanxi University (Natural Science Edit, 2009, 32(3) | |
| Authors: | XIA Dao-cheng YAO Ji-huan BAI Qing-long CHENG Chuan-hui XIA Dao-peng LIU Li-feng FAN Zhao-qi DU Guo-tong |
| Abstract: | The synthesis and characterizations of Sub-phthalocyanine copper were reported in this paper firstly. The mixture of 1,3-diiminoisoindoline and Cu(AcO)_2 · 2H_2O was added to quinoline under stirring. Then, a catalytic amount of 1,8-Diazabicyclo [5,4,0]undec-7-ene (DBU) was added. The collected solid powder were extracted with anhydrous methanol in a Soxhlet extractor and further purified by chro-matography. Sub-Phthalocyanine copper was characterized by MS and elemental analysis. The results were agreement with the proposed structures. The Sub-phthalocyanine copper molecular was broken by laser which was shown in Mass Spectrum. It was analyzed that this material decomposition process,and proposed the reaction mechanism through the broken of Sub-phthalocyanine copper molecular. |
| Keywords: | phthalocyanine sub-phthalocyanine copper reaction mechanism |
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