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Thiol- and Disulfide-Based Stimulus-Responsive Soft Materials and Self-Assembling Systems
Authors:Danielle M Beaupre  Richard G Weiss
Institution:1.Department of Chemistry, Georgetown University, Washington, DC 20057, USA;2.Institute for Soft Matter Synthesis and Metrology, Georgetown University, Washington, DC 20057, USA
Abstract:Properties and applications of synthetic thiol- and disulfide-based materials, principally polymers, are reviewed. Emphasis is placed on soft and self-assembling materials in which interconversion of the thiol and disulfide groups initiates stimulus-responses and/or self-healing for biomedical and non-biomedical applications.
Keywords:stimulus-responsive materials  self-healing  redox-responsive  drug delivery  thiol-disulfide exchange  disulfide-disulfide metathesis
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