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Syntheses Based on Natural α-Amino Acids. Cyanoethylation of 3-Substituted 5-Methyl-2-thiohydantoins
Authors:A T Ayupova  Kh M Shakhidoyatov
Institution:(1) S. Yunusov Institute of Chemistry of Plant Substances, Academy of Sciences, Republic of Uzbekistan, Tashkent, 700170
Abstract:Starting from α-alanine, the C- and S-cyanoethyl derivatives of 5-methyl-3-phenyl(allyl)-2-thiohydantoins have been synthesized. It was shown that the products of hydrolysis of C-cyanoethyl derivatives, 5-methyl-3-phenyl(allyl)-(β-carboxyethyl)-2-thiohydantoins, are formed in addition. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1657–1661, November, 2005.
Keywords:acrylonitrile  α  -alanine  2-thiohydantoin  cyanoethylation
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