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Structural requirements for efficient photoinduced electron transfer (PET) quenching in 9-aminoalkylanthracenes
Authors:John C. Beeson  Michael E. Huston  Douglas A. Pollard  T. K. Venkatachalam  Anthony W. Czarnik
Affiliation:(1) Department of Chemistry, The Ohio State University, 43210 Columbus, Ohio
Abstract:The structure-quenching relationship in 9-aminoalkylanthracenes is examined by the synthesis and fluorescence evaluation of five derivatives; it is observed that benzylic 2° and 3° amines lead to ge95% quenching of anthracene fluorescence in water, while other amines afford substantially lower quenching efficiencies.
Keywords:Photo induced electron transfer (PET) quenching  9-aminoalkylanthracenes  structure
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