Synergic liquid-liquid extraction studies of neodymium and praseodymium with mixtures of tributyl phosphate and Aliquat-336 in nitrate media |
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Authors: | A. G. Gaikwad A. D. Damodaran |
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Affiliation: | (1) Regional Research Laboratory, (CSIR), 695 019 Trivandrum, India;(2) Present address: Department of Analytical Chemistry, Faculty of Science, University of Cordoba, 14004 Corboda, Spain |
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Abstract: | Extraction studies of neodymium and praseodymium with mixtures of tributyl phosphate and Aliquat-336 in xylene have been carried out. From 3.0M aqueous ammonium nitrate solutions, negatively charged complexes of neodymium and praseodymium were extracted with Aliquat-336 in the presence of tributyl phosphate into the organic phase. The synergic extracted species observed was M(NO3)4–L+·TBP. The synergic extraction of lanthanide elements in nitrate media increases from lanthanum to lutetium. |
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