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Vacuum ultraviolet resonance line radiation source from rare gas atoms and ions for UHV photoelectron spectroscopy
Authors:GM Lancaster  JA Taylor  A Ignatiev  JW Rabalais
Institution:Departments of Chemistry and Physics, University of Houston, Houston, Texas 77004 U.S.A.
Abstract:A source and differential pumping system for producing high intensity resonance line radiation from rare gas atoms and ions for ultrahigh vacuum (UHV) photoelectron spectroscopy has been developed. Photoelectron count rates from a gold sample, as measured with a double-pass cylindrical mirror analyzer at pass energy 15 eV and 0.10 eV resolution, are ~ 300,000 c s?1 for the He(I) (21.22 eV) line and ~30000 c s?1 for the He(II) (40.81 eV) line. The source design is based on the principle of the electrostatic charged particle oscillator and is capable of sustaining discharges over the pressure range 1 to ~ 10?6 torr. The discharge segment consists of a cylindrical cold cathode surrounding two tungsten rod anodes which are held at high positive potential. Three stages of differential pumping are employed in order that the vacuum in the main spectrometer chamber can be maintained at 2 × 10?10 torr during operation. The calculated helium flow reaching the main chamber under these conditions is < 101 s?1. Details of the construction and operating characteristics of the source are presented.
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