He(I) and He(II) photoelectron spectra of some substituted ethylenes |
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| Authors: | H. Van Dam A. Oskam |
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| Affiliation: | Universiteit van Amsterdam, Anorganisch Chemisch Laboratorium, J. H. van ''t Hoff Instituut, Nieuwe Achtergracht 166, Amsterdam The Netherlands |
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| Abstract: | The He(I) and He(II) photoelectron spectra of acrolein, acrylic acid, methyl acrylate, vinyl acetate, acrylamide and some of their methyl-substituted analogues are reported. Detailed assignments are proposed, mainly based on differences in intensity between the He(I) and He(II) spectra, on sum rule considerations and on the results of modified CNDO/S calculations.The assignment criteria are critically evaluated. |
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| Keywords: | To whom correspondence should be addressed. |
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