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| 直接甲酸燃料电池用碳载铁卟啉-Au复合阴极催化剂的性能 | |
| 引用本文： | 马德娜,陈 卫,焦连升,唐亚文,刘长鹏,邢 巍,陆天虹.直接甲酸燃料电池用碳载铁卟啉-Au复合阴极催化剂的性能[J].无机化学学报,2008,24(11):1803-1806. |
| 作者姓名： | 马德娜 陈 卫 焦连升 唐亚文 刘长鹏 邢 巍 陆天虹 |
| 作者单位： | 1. 江苏省生物功能材料重点实验室,南京师范大学化学与环境科学学院,南京,210097 2. 承德民族师范专科学院化学系,承德,067000 3. 中国科学院长春应用化学研究所,长春,130022 4. 江苏省生物功能材料重点实验室,南京师范大学化学与环境科学学院,南京,210097;中国科学院长春应用化学研究所,长春,130022 |
| 基金项目： | 国家高技术研究发展计划(863计划)，国家自然科学基金，江苏省自然科学基金 |
| 摘 要： | 研究了用于直接甲酸燃料电池(DFAFC)的碳载铁卟啉(FeTPP/C)、金复合阴极催化剂(FeTPP-Au/C)对氧还原的电催化性能和抗甲酸能力。结果表明，FeTPP-Au/C催化剂对氧气还原反应的电催化活性要远优于碳载铁卟啉(FeTPP/C)和碳载Au(Au/C)催化剂。而且，FeTPP-Au/C催化剂对甲酸氧化没有催化活性，因此，FeTPP-Au/C催化剂也有很好的抗甲酸能力。所以，FeTPP-Au/C催化剂适合作为DFAFC的阴极催化剂。 |
| 关 键 词： | 直接甲酸燃料电池 铁卟啉 金 阴极催化剂 氧还原 |
Performance of Carbon Supported Fe-tetraphenylporphrin-Au as Cathodic Catalyst in Direct Formic Acid Fuel Cell |
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| MA De-N,CHEN Wei,JIAO Lian-Sheng,TANG Ya-Wen,LIU Chang-Peng,XING Wei and LU Tian-Hong.Performance of Carbon Supported Fe-tetraphenylporphrin-Au as Cathodic Catalyst in Direct Formic Acid Fuel Cell[J].Chinese Journal of Inorganic Chemistry,2008,24(11):1803-1806. | |
| Authors: | MA De-N CHEN Wei JIAO Lian-Sheng TANG Ya-Wen LIU Chang-Peng XING Wei and LU Tian-Hong |
| Abstract: | The electrocatalytic performance for the oxygen reduction and formic acid tolerance ability of the carbon supported catalyst of iron tetraphenylporphyrin (FeTPP) and Au (FeTPP-Au/C) were investigated. The results indicate that the electrocatalytic activity of the FeTPP-Au/C catalyst for the oxygen reduction is much better than that of the FeTPP/C and Au/C catalyst. In addition, the FeTPP-Au/C catalyst has no electrocatalytic activity for the oxidation of formic acid. Thus, it possesses high formic acid tolerance ability suitable to be used as the cathodic catalyst in DFAFC. |
| Keywords: | direct formic acid fuel cell iron tetraphenylporphyrin gold cathodic catalyst oxygen reduction |
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