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Reaction of Tricarbonyl(η3-allyl)iron(0) Anions with Bromine |
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| Authors: | Ming-Chang P Yeh Kuo-Ping Kang Chong-Chen Hwu |
| Abstract: | The addition of reactive carbanions to tricarbonyl(η4-1,3-diene)iron(0) complexes proceeded at 23°C to give putative tricarbonyl(η3-allyl)iron(0) anion complexes. Trapping of the reactive intermediates with bromine produced nucleophilic-substituted tricarbonyl(η4-1,3-diene)iron(0) complexes. |
| Keywords: | Tricarbonyl(η 3-allyl)iron(0) anionic complexes β -Hydride elimination Reductive elimination (η 3-Allyl) syn/anti isomerization |