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Studies of tris[(phenyldimethylsilyl)methylene]-tin carboxylates
Authors:Qing-Lan Xie  Jing Li  Zhl-Qiang Yang  Dian-Kun Zhang  Ji-Tao Wang
Abstract:Twenty-six derivatives of tris(phenyldimethylsilyl)methylene]tin carboxylates have been prepared. All compounds are new and characterized through elemental analysis IR spectra, and 1H, 13C, 110Sn NMR spectral studies. The spectral results showed that all compounds are four coordinated organotin compounds. The Δv (=υurn:x-wiley:1001604X:media:CJOC19910090407:tex2gif-stack-1urn:x-wiley:1001604X:media:CJOC19910090407:tex2gif-stack-2) of them are over 300 cm?1. The chemical shifts (δ) of 119Sn of ArCO2Sn(CH2SiMe2Ph)3 and ArOCH2CO2Sn(CH2SiMe2Ph)3 give good straight-line correlation with para-substituent constants. These compounds have good acaricide activity, but their action on the mite are slower than that of Torque.
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