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Rate constant and products of the BrO + BrO reaction at 298 K
Authors:I T Lanar  G Laverdet  G Le Bras  G Poulet
Institution:I. T. Lançar,G. Laverdet,G. Le Bras,G. Poulet
Abstract:The overall rate coefficient k of the self recombination of BrO radicals has been measured at 298 K with use of the discharge flow/mass spectrometry technique. The rate coefficient k2 for the reaction channel forming Br2 has been also determined. The results are: k = (3.2 ± 0.5) × 10?12 and k2 = (4.7 ± 1.5) × 10?13 (in cm3 molecule?1 s?1). These results are discussed with respect to previous literature data.
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