Identification,synthesis and conformational study of a CN(R,S) synthon by-product: (5R, 10R)-5,10-diphenyl-1,6-diaza-3,8-dioxabicyclo[4.4.1]undecane |
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Authors: | David J. Aitken,Dominique Guillaume,Henri-Philippe Husson,Ang le Chiaroni,Claude Riche |
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Affiliation: | David J. Aitken,Dominique Guillaume,Henri-Philippe Husson,Angèle Chiaroni,Claude Riche |
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Abstract: | The title compound, containing a new heterocyclic skeleton, was identified by X-ray crystallography as the product of condensation of (R)-phenylglycinol with an excess of formaldehyde. The molecule adopts a rigid double twist-chair conformation in both solid and solution states. |
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