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New Synthetic Route to Polyhedral Organylsilsesquioxanes |
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| Authors: | Daniel Herren,Heribert Bü rgy,Gion Calzaferri |
| Abstract: | Hydrosilation of methylenecyclohexane and hex-1-ene by octa(hydridosilsesquioxane) catalysed by hexachloroplatinic acid is a new route to polyhedral organylsilsesquioxanes. Quantitative yield of octa(cyclohexylmethylsilsesquioxane) is reached. This reaction opens a vast field of yet unknown polyhedral silsesquioxanes. |
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