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Highly stereoselective approach toward the synthesis of the macrolactone core of amphidinolide W |
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| Authors: | Debendra K Mohapatra Bhaskar Chatterjee Mukund K Gurjar |
| Institution: | Division of Organic Chemistry, National Chemical Laboratory, Pune, Maharashtra 411 008, India |
| Abstract: | The diastereoselective synthesis of the macrolactone core of amphidinolide W was successfully accomplished using Evans’ asymmetric alkylation, Aldol reaction, Julia-Kocienski olefination, and Kita’s macrocyclization protocol. |
| Keywords: | Amphidinolide W Evans alkylation Evans aldol Julia-Kocienski olefination Kita&rsquo s macrocyclization |
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