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A facile method for the preparation of hexafluoroisopropanol functionalized derivatives using hexafluoroacetone trihydrate via a carbonyl-ene reaction
Authors:Madabhushi Sridhar  Chinthala Narsaiah  Vishnu M. Ankathi  Shrinandan N. Asthana
Affiliation:a Fluoroorganics Division, Indian Institute of Chemical Technology, Hyderabad 500 007, India
b High Energy Materials Research Laboratory, Sutarwadi, Pune 411 021, India
Abstract:Hexafluoroacetone trihydrate was shown to undergo an efficient carbonyl-ene reaction with a variety of alkenes in the presence of molecular sieves under microwave heating and conventional heating producing hexafluoroisopropanol functionalized derivatives in high yields.
Keywords:Hexafluoroisopropanol functionalized derivatives   Carbonyl-ene reaction   Alkenes   Hexafluoroacetone trihydrate   Molecular sieves   Microwave reaction
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