Cyclopropane ring-opening of tricyclo[3.3.0.0]octan-3-ones: a quick access to bicyclo[3.2.1]octanones from 2-methoxyphenols |
| |
| Authors: | Chun-Ping Chang Gary Jing Chuang |
| |
| Institution: | a Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan
b Department of Chemistry, Chung Yuan Christian University, Chungli 32023, Taiwan |
| |
| Abstract: | We herein report an efficient and rapid strategy for the synthesis of highly functionalized bicyclo3.2.1]octanones via sequential reactions: Diels-Alder reaction of MOB—ODPM rearrangement—reductive cleavage of cyclopropane, and its application to synthesize the core structure of drechslerine D. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
