Carboalumination/Ni-catalyzed couplings. A short synthesis of verticipyrone |
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| Authors: | Bruce H. Lipshutz Benjamin Amorelli |
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| Affiliation: | Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106, USA |
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| Abstract: | Verticipyrone (1) has been synthesized in six overall steps from commercially available ethyl-2-methylacetoacetate. This represents the first successful application of a modified Negishi carboalumination-nickel-catalyzed cross-coupling reaction to a chloromethylated pyrone. |
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