α-Allylation of α-amino acids via 1,5-hydrogen atom transfer |
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| Authors: | Muhammad I. Chowdhry Michael B. Hursthouse |
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| Affiliation: | a School of Biosciences, University of Exeter, Geoffrey Pope Building, Stocker Road, Exeter, EX4 4QD, UK
b EPSRC X-Ray Crystallography Service, Department of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK |
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| Abstract: | A straightforward method for the radical-based α-allylation of proteinogenic α-amino acids is described in which the key step involves 1,5-hydrogen atom transfer from the C-4 position of an oxazolidin-5-one. |
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