Intramolecular nucleophilic substitution at an sp carbon: synthesis of substituted thiazoles and imidazole-2-thiones |
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| Authors: | Shu-Su Shen |
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| Affiliation: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore |
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| Abstract: | The nucleophilic substitution reactions of vinylic bromides with intramolecular thioamide or thiourea moieties proceed to give a series of substituted thiazoles and imidazole-2-thiones. |
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| Keywords: | Intramolecular nucleophilic substitution Vinylic substitution Thiazoles Imidazole-2-thiones |
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