|
|||||
|
|
Ring opening of unprotected aziridines by zinc selenolates in a biphasic system |
|
| Authors: | Antonio L. Braga Ricardo S. Schwab Syed M. Salman Juliano B. Azeredo |
| Affiliation: | a Departamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS, Brazil b Departamento de Química, Universidade Federal de Santa Catarina, Florianópolis, SC, Brazil |
| Abstract: | A set of chiral β-seleno amines were prepared by the ring-opening reaction of unprotected aziridines. Under acid conditions diaryl or dialkyl diselenides were reduced by zinc and treated with unprotected aziridines to produce the desired products in good yields. Chiral β-telluro amine was also obtained using this method. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |