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An efficient and stereoselective route to 1-deoxy-5-hydroxy sphingosine analogues |
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| Authors: | Partha Pratim Saikia |
| Affiliation: | Natural Products Chemistry Division, North East Institute of Science and Technology, Jorhat 785 006, India |
| Abstract: | A short and efficient synthesis of 1-deoxy-5-hydroxy sphingolipid is described. The key steps involved are a Jacobsen hydrolytic kinetic resolution (HKR) and Shibasaki’s asymmetric Henry reaction. |
| Keywords: | Sphingolipids Asymmetric synthesis Asymmetric Henry reaction Hydrolytic kinetic resolution Regioselective ring opening |
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