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Synthesis and self-assembly of a triphenylene-containing amphiphilic conjugated macrocycle
Authors:Degang Wang  Mahuya Bagui  Yong Wang  Andrew J Holder
Institution:a Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA
b Department of Oral Biology, University of Missouri-Kansas City, Kansas City, MO 64110, USA
Abstract:A new amphiphilic π-conjugated system containing a shape-persistent conjugated macrocycle with two triphenylene chromophores as the anchoring units has been successfully synthesized. The amphiphilic macrocycle has been found to self-assemble into robust and uniform microspheres, presumably due to the strong π−π stacking interaction between triphenylene chromophores.
Keywords:Triphenylene  Macrocycle  Amphiphilic
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