Improved hydrogen generation from formic acid |
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| Authors: | Henrik Junge Francesca Capitta James R. Noyes Matthias Beller |
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| Affiliation: | a Leibniz-Institut für Katalyse e. V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29A, D-18059 Rostock, Germany
b Dipartimento di Chimica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy |
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| Abstract: | The ruthenium-catalyzed generation of hydrogen from formic acid was investigated in the presence of amines and halide additives. While amidines and halide additives increase the production of hydrogen with [RuCl2(p-cymene)]2, >330 mL hydrogen/h is generated in the presence of [RuCl2(benzene)]2/dppe and N,N-dimethyl-n-hexylamine. |
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| Keywords: | Catalysis Formic acid Hydrogen Ruthenium |
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