Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes |
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Authors: | Zh V Dobrokhotova I G Fomina M A Kiskin A A Sidorov V M Novotortsev I L Eremenko |
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Institution: | (1) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation |
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Abstract: | Solid-phase thermal decomposition of polynuclear NiII and CoII pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear
(from bi-to hexanuclear) CoII carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear
NiII carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the
nature of coordinated ligands.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 250—260, February, 2006. |
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Keywords: | polynuclear complexes cobalt and nickel complexes carboxylate ligands thermal decomposition |
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