Nitrosation of Dodecahydro-closo-Dodecaborate Anions in Aqueous and Nonaqueous Solutions |
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| Authors: | Zhizhin K. Yu. Votinova N. A. Goeva L. V. Kuznetsov N. T. |
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| Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia |
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| Abstract: | Nitrosation of dodecahydro-closo-dodecaborate anions with nitrous acid in an aqueous solution and with isoamyl nitrite and nitrosyl chloride in nonaqueous solutions was studied. The main reaction product is the mononitrosoundecahydro-closo-dodecaborate anion. Conditions were selected for the preparation of the nitroso-substituted anion in the highest yield as alkylammonium, tetraphenylphosphonium, and alkali-metal salts. The salts were studied using IR, UV, and 11B NMR spectroscopy. |
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