Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide |
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| Authors: | Chas Marcos Lemarié Margareth Gulea Mihaela Avarvari Narcis |
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| Affiliation: | Laboratoire Chimie, Ingénierie Moléculaire et Matériaux (CIMMA), UMR 6200 CNRS-Université d'Angers, UFR Sciences, Bat. K, 2 Bd. Lavoisier, 49045 Angers, France. |
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| Abstract: | Selective sulfoxidation of BEDT-TTF (bis(ethylenedithio)-tetrathiafulvalene) with enantiopure (camphoryl-sulfonyl)oxaziridine derivatives provided the inner monosulfoxide, as demonstrated using single crystal X-ray analysis, with an enantiomeric excess of 44% (up to 74% after recrystallization). |
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