ESR studies of slow relaxations of the rate of sulfur dioxide oxidation on vanadium catalyst |
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| Authors: | S V Kozyrev B S Balzhinimaev G K Boreskov A A Ivanov and V M Mastikhin |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Slow changes in the rate of the title reaction are shown to be due to pahse transformations of the active component, in particular, the agglomeration or crystallization of vanadyl complexes. The possible mechanism of these phenomena is discussed.
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