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Synthesis of fulleropyrrolidines through the reaction of [60]fullerene with quaternary ammonium salts and amino acids |
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| Authors: | Bo Jin Ru-Fang Peng Juan Shen Shi-Jin Chu |
| Institution: | aDepartment of Chemistry, Southwest University of Science and Technology, Mianyang 621010, China;bSchool of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China;cAnalytical & Testing Center, Sichuan University, Chengdu 610064, China |
| Abstract: | The reactions of 60]fullerene with amino acids and quaternary ammonium salts in toluene afforded two fulleropyrrolidine derivatives. One fulleropyrrolidine derivative contained a RCH moiety originating from quaternary ammonium salts through C–N bond cleavages and other fulleropyrrolidine derivatives contained a PhCH moiety originating from toluene through C–H bond cleavage. By using chlorobenzene instead of toluene as solvent, only one fulleropyrrolidine derivative containing a RCH moiety was obtained in the reactions. |
| Keywords: | Fullerene Amino acids Cycloaddition reaction Quaternary ammonium salts |
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