Reactions of titanium alcoholates Ti(OR)4 (R = n-Bu, t-Bu) with tertiary organic and organometallic hydroperoxides |
| |
Authors: | L. P. Stepovik M. V. Gulenova |
| |
Affiliation: | (1) Lobachevsky Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia |
| |
Abstract: | tert-Butyl and cumyl hydroperoxides in the reactions with Ti(OR)4 are reduced to alcohols with the evolution of oxygen via formation of titanium-containing peroxides and trioxides. The pathways of the reactions of Ti(OR)4 with triphenylelement hydroperoxides R3EOOH (E = C, Si, Ge) depend on element E and on the structure of R; the reactions involve the rearrangement of the peroxides, and with (n-BuO)4Ti the alkoxy group is oxidized either with preservation or with breakdown of the hydrocarbon skeleton. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|