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Dynamics of polar solvation: Route to single exponential relaxation via translational diffusion |
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| Authors: | Biman Bagchi and Amalendu Chandra |
| Institution: | (1) Solid State and Structural Chemistry Unit, Indian Institute of Science, 560 012 Bangalore, India |
| Abstract: | A microscopic theoretical calculation of time-dependent solvation energy shows that the solvation of an ion or a dipole is dominated by a single relaxation time if the translational contribution to relaxation is significant. Contribution No. 545 from the Solid State and Structural Chemistry Unit |
| Keywords: | Polar solvation single exponential relaxation translational diffusion time-dependent solvation energy |
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