Apparent molal heat capacities of organic solutes in water. V. aminoalcohols,aminoethers, diamines,and polyethers |
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Authors: | Sergio Cabani Sheila T Lobo Enrico Matteoli |
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Institution: | (1) Istituto di Chimica Fisica, Università di Pisa, Via Risorgimento 35, 56100 Pisa, Italy;(2) Laboratorio di Chimica Quantistica ed Energetica Molecolare del C.N.R., Via Risorgimento 35, 56100 Pisa, Italy |
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Abstract: | Apparent molal heat capacities of 20 organic uncharged compounds in aqueous solution have been determined at 25 and 40°C. The substances studied include mono- and polyfunctional ethers, and bifunctional open-chain compounds like aminoalcohols, aminoethers, and diamines. The results obtained support the presence of interaction between water and the hydrophilic groups –O–, –NH2, –NH–, and
, and evidence indicates that these interactions strongly depend on the molecular structure of the compound containing the functional group. |
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Keywords: | Apparent molal heat capacities aqueous solutions solute-water interactions ethers aminoethers aminoalcohols diamines |
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