Neutron diffraction experiments on CsCrI3 at 300, 77, and 1.2°K: H. W. Zandbergen and D. J. W. Ijdo. Gorlaeus Laboratories,University of Leiden,P.O. Box 9502, 2300 RA Leiden,The Netherlands |
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Authors: | John Koenitzer Bijan Khazai Jacob Hormadaly Robert Kershaw Kirby Dwight Aaron Wold |
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Institution: | Department of Chemistry, Brown University, Providence, Rhode Island 02912 USA |
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Abstract: | The orthorhombic α-PbO2 phase of FeNbO4 was prepared and its photoelectronic properties measured: Sintered disks were shown to be n type and gave a resistivity of 40 Ω-cm. Measurements of the photoresponse gave a flat-band potential between 0.1 and 0.4 V vs SCE at a pH of 8.5 and an optical band gap of 2.08(2) eV. Several higher-energy band gaps at 2.68(2), 2.94(2), 3.24(2), and 4.38(2) eV were also determined. There appears to be an enhancement of the quantum efficiency due to the presence of FeO6] active centers while retaining the fundamental characteristics of the NbO6] octahedra. |
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Keywords: | To whom all correspondence should be addressed |
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