| STABILITY OF POLY（N,N＇-METHYLENEBISACRYLAMIDE-co-4-VINYLPYRIDINE） MICROGEL DISPERSION AND ADJUSTMENT OF THE HYDROPHOBICITY IN THE MICROGELS |
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| 作者姓名： | Qing-de Chen Xing-hai Shen |
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| 作者单位： | Departmentof-Applied Chemistry. College of Chemistry and Molecu-lar Engineering, Peking University, Beijing 100871, China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China （Nos. 90206020 and 29901001）. |
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| 摘 要： | In the UV-Vis spectra of pure light-scattering systems, there is an exponential relationship between absorbance and wavelength （A = Kλ^-n）. Here, the exponent n is named as flocculation-coagulation parameter. In the present paper, the effects of different additives on the stability of poly（N,N＇-methylenebisacrylamide-co-4-vinylpyridine） （poly（Bis-co-4-VP）） microgel dispersion were studied in detail via this parameter. The results showed that the stability of the dispersion mainly comes from the ionization of pyridine groups, making the microgel positively charged on its surface. This was confirmed by the measurement of Zeta potential and the result of conductometric titration. The result of fluorescence analysis indicated that the hydrophobicity in the microgels is enhanced with the increase in total 4-VP unit content.
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| 关 键 词： | 乙烯基吡啶 凝结物 聚合作用 杂环化合物 |
| 收稿时间： | 2004-11-29 |
| 修稿时间： | 2005-01-28 |
Stability of Poly(N,N-methylenebisacrylamide-co-4-vinylpyridine) Microgel Dispersion and Adjustment of the Hydrophobicity in the Microgels |
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| Qing-de Chen Xing-hai Shen.Stability of Poly(N,N-methylenebisacrylamide-co-4-vinylpyridine) Microgel Dispersion and Adjustment of the Hydrophobicity in the Microgels[J].Chinese Journal of Polymer Science,2005,0(6):635-642. |
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| Authors: | Qing-de Chen Xing-hai Shen Hong-cheng Gao |
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| Institution: | Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China |
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| Abstract: | In the UV-Vis spectra of pure light-scattering systems, there is an exponential relationship between absorbance and wavelength ( ). Here, the exponent n is named as flocculation-coagulation parameter. In the present paper, the effects of different additives on the stability of poly(N,N-methylenebisacrylamide-co-4-vinylpyridine) (poly(Bis-co-4-VP)) microgel dispersion were studied in detail via this parameter. The results showed that the stability of the dispersion mainly comes from the ionization of pyridine groups, making the microgel positively charged on its surface. This was confirmed by the measurement of Zeta potential and the result of conductometric titration. The result of fluorescence analysis indicated that the hydrophobicity in the microgels is enhanced with the increase in total 4-VP unit content. |
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| Keywords: | Microgel dispersion(s) 4-Vinylpyridine Flocculation-coagulation parameter Zeta potential |
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